# Study on the creep behavior of bonded metallic joints

- Rodrigo A Queiroz
^{1}Email author, - Eduardo M Sampaio
^{1}, - Vitor J Cortines
^{1}and - Ney RF Rohem
^{2}

**2**:8

**DOI: **10.1186/2196-4351-2-8

© Queiroz et al.; licensee Springer. 2014

**Received: **13 September 2013

**Accepted: **11 December 2013

**Published: **25 March 2014

## Abstract

Bonded joints have been used as the main alternative to join components made of different materials or not. Literature shows that although prior studies focused on the characterization of several mechanical properties related to joints, little is known about the creep behavior of bonded joints. Creep test’s main disadvantage is the low productivity of results since testing machines are not able to perform simultaneous multiple tests. In this case, the statistical treatment is based on a small amount of results, reducing the reliability of the predictions obtained. With this in mind, the Laboratory of Adhesion and Adherence (LAA) developed the pneumatic creep equipment (PCE), capable of testing ten specimens simultaneously, with distinct parameters. This work studies the behavior of single-lap joints (SLJ) made of metallic substrate and bonded with epoxy and polyurethane adhesives. The joints were fabricated in conformity with the ASTM D 1002 standard. Results show that, for long term applications, the average tensile strength isn’t enough to guarantee project safety. An initial model for the creep behavior of bonded joints is proposed.

### Keywords

Creep Bonded joints Epoxy Polyurethane## Background

The use of structural adhesives in bonded joints is becoming more and more important in the industry, especially by being an alternative to join components which cannot be exposed to extreme thermal variation. The technique is already widely used in the aerospace industry, mainly because of its reduced weight and relatively high mechanical strength, characteristics that also appeal to the industry as a whole.

Many studies have focused on the behavior of the stress distribution along the joint [1–3], its failure mechanisms [4–6], the influence of substrate surface treatment [7, 8], shape factors of the bonded area [9, 10] and ways to increase the mechanical strength of the joint. However, little is known about its time dependent behavior when statically loaded, in other words, its behavior under creep.

Defined as a time dependent permanent deformation of materials submitted to loads or strains, creep is generally a unwanted phenomenon, and is frequently a limiting factor regarding a components lifespan [11].

Amorphous polymers such as plastics and rubbers are especially sensitive to creep deformation [11]. Even though observed in all kinds of materials, an analysis of the state of the art shows that the great majority of the documented work on creep behavior has been done focusing on metallic and ceramic materials, mainly at high temperatures.

This work aims to contribute to a better understanding of the creep behavior of polymeric adhesives. Due to the small number of related researches in this matter, our starting point will be the much more documented behavior of creep in metallic materials, which will be used to introduce some concepts.

Frequently, the most important parameter of creep testing of materials is the determination of the creep rate under a steady state ${\dot{}}_{r}$. This engineering parameter is taken into account in long term applications, when temperature is above 40% the absolute melting point of the material, and when large deformations cannot occur [12]. On the other hand, in many situations of creep with relatively short duration, the timespan until rupture is the prevailing project consideration.

Both the level of strain and the temperature level influence the creep behavior of materials. Increases in temperature generally mean an increase in the creep rate and in a reduction of the lifespan until failure.

*K*

_{ 1 }and

*n*are constant to a given material [11].

*K*

_{ 2 }and

*Q*

_{ f }constants.

*Q*

_{ f }is the creep activation energy, and is dependent of theoretical mechanisms such as strain induced vacancy diffusion, crystal boundary diffusion, among others proposed in order to explain creep behavior of various materials. Each mechanism takes a different strain exponent,

*n*. It has been possible to elucidate the creep mechanism for a specific material by comparing its experimental value

*n*with the estimated value for different mechanisms [11].

Quite frequently, it comes up the need to use creep data for project purposes but it is not easy to obtain such data with a conventional laboratory testing. This is particularly true when it comes to prolonged exposure time. An alternative is to carry out creep testing under higher temperatures in order to compensate for shorter testing times, while the testing loads remain the same. This way it is possible to extrapolate the data to real operating conditions [11].

- a)
Pneumatic cylinder: it is responsible for applying the load;

- b)
Pressure regulator: it has an analogical manometer and a valve responsible for controlling the cylinder’s internal pressure, and thus, the load applied to the test specimen;

- c)
Hour counter: it is responsible for monitoring the test duration. When the specimen fails, a sensor is triggered stopping counting;

- d)
Adjustable pliers: the upper pair of pliers can be adjusted to various heights, according to the length of the specimens to be tested. They were designed to be in accordance to the joint standards determined by ASTM D 1002 [13] and ASTM 638 M [14];

The equipment is connected to a pressurized line that feeds all the testing units. Its working principle is to convert pneumatic pressure into load at the piston rod. The load applied to the joint can be adjusted by varying the pressure in each cylinder’s upper chamber. The equipment was calibrated using SHIMADZU’s universal testing machine AG-X Plus as reference.

## Methods

The main objective of this work was to determine the lifespan of the single lap joints (SLJ) as a function of the applied loads.

The first variable, implicit to the study, corresponds to the loads to which the joints will be submitted, and the second variable corresponds to both adhesives selected for the study, an epoxy based one, with greater tensile modulus, and a polyurethane based one, with lower tensile modulus.

**Characteristics of the epoxy based adhesives**

Working time | 10 min. (25°C) |
---|---|

Texture | Pasty |

Volumetric mixture ratio | 5:1 |

Polimeric basis | Epoxy |

Post mixture color | Dark grey |

Tensile modulus | 14 GPa |

Ultimate strength | 40 MPa (± 10) |

Curing conditions | 24 hours in an oven 40°C |

Relative humidity | 60% |

**Characteristics of the polyurethane based adhesives**

Working time | 5 min. (25°C) |
---|---|

Texture | Viscous liquid |

Volumetric mixture ratio | 1:1 |

Polimeric basis | Urethane |

Post mixture color | Light grey |

Tensile modulus | 0,8 GPa |

Ultimate strength | 9 MPa (± 6) |

Curing conditions | 24 hours in an oven 40°C |

Relative humidity | 60% |

Before starting the tests it was necessary to know the average tensile strength (**τ**_{
u
}) of the bonded joints for each adhesive tested, epoxy and polyurethane. The obtained value **τ**_{
u
} was used as a reference and considered as the maximum load that each joint could withstand.

The selected load levels where of 90; 80; 70; 60; 50% of **τ**_{
u
} for creep testing. However, during the tests, intermediate loads were needed in order to investigate the dispersion of the results. For each load, at least three samples were tested.

The average test duration for the groups tested under the same load was considered as the lifespan for that load level. This allowed to build a curve in order to represent the behavior of the joints related to *load* x *lifespan*.

**Final conditions of the samples after bonding**

Total length [mm] | Width [mm] | Overlap length [mm] | Adhesive thickness [mm] |
---|---|---|---|

189.8 (±0.3) | 25.4 (±0.1) | 13.0 (±0.1) | 0.5 (±0.1) |

Surface roughness measures, using the Rt parameter, were made using the three-dimensional rugosimeter TalysScan 150 (Taylor Hobson), with scanning speed of 1000 μm/s and a x-y grid precision of 1 × 10 μm. The measuring area was 4 × 0.01 mm, according to the standard ISO 4288:1996. The average roughness found was of 102.4 μm with standard deviation of 18.6.

To determine the average tensile strength (**τ**_{
u
}) of the joints, ten test specimen for each adhesive were tested in the universal testing machine, according to the referenced parameters of the ASTM 1002 standard.

## Results and discussions

The resulting data analysis of the ten test specimen using epoxy adhesive established **τ**_{
u
} as 14.1 MPa, with standard deviation of 5.2.

**τ**

_{ u }respectively. A minimum of three test samples were used for each of the load levels, being all the tests carried out at 20°C (± 2.5°C) temperature. Table 4 presents the results regarding the average lifespan of the test pieces as a function of the loads to which they were subject. The 14.1 MPa load corresponds to the established τ

_{ u }.

**Results of the creep testing with loads of 100%, 80% and 70% of τ**
_{
u
}
**for EPOXY adhesives**

EPOXY adhesives | Load [MPa] | Time until rupture [hours] | |||
---|---|---|---|---|---|

Average | Standard deviation | Average | Standard deviation | ||

100 | % of τ | 14.1 | 5.2 | 0.2 | 5.7 |

80 | % of τ | 11.4 | 3.5 | 8.0 | 169.7 |

70 | % of τ | 9.9 | 4.0 | 1768.5 | 47.8 |

60 | % of τ | 8.5 | 4.2 | 2334.0 | 0.0 |

As it has been largely published, tests performed as a function of time have as a common characteristic high standard deviation values. In Table 4, the test performed under a 11.4 MPa load showed standard deviation in the order of 170. However, it is possible to observe that the average lifespan under such loads was of 8 hours, an insignificant lifespan when long term bonding is considered. Thus, the greatest data dispersion occurred in a region of very little interest.

The tests performed under a 9.9 MPa showed a different behavior if compared to the previous one. An expressive increase in the joints lifespan was observed, going from 8 hours to 1280.8 hours in average.

The analysis of the results from 14.1 MPa to 9.9 MPa showed two regions with different slopes. The primary region, the 14.1 MPa to 11,4 MPa interval, presented a steep negative slope and extremely small periods of time indicating high mechanical strength reduction rates at loads near the joints τ_{
u
}. The secondary region, the 11.4 MPa to 9.9 MPa interval, showed small mechanical strength reduction rates, indicating a tendency to stabilization of the curve at 9.9 MPa, reinforced by the fact that two of the five joints tested endured 2500 hours without failure before the test was interrupted.

The test related to the 8.5 MPa loads are still in progress, and the partial results indicate a tendency to overcome 3000 hours without any of the test specimens presenting failure.

Not considering the lower load value data points, related to 8.5 MPa load, for which the joints are still being tested, it is possible to use the linear regression technique adapted to the logarithm to determine the n_{
1
} and k_{
1
} coefficients from Equation 3. They are responsible for adjusting the line model to the data points so that de square deviation of the data points may be minimized in relation to the line. The variable τ represents the shear stress of the joints; t_{
r
} the lifespan until failure; and the constants k_{
1
} e n_{
1
}, the slope and position of the model curve.

Where:

n_{
1
} = -3.83 × 10^{-2};

k_{
1
} = 12.84 MPa/h;

As shown, for the 9.9 MPa load, the gap between the upper and lower limits related to the lifespan is rather large, however, as represented by the model, the point is located in the curve stabilization region, where small variations on the load, in the same order as the equipment’s resolution, would have a strong influence on the joints lifespan.

Substituting the values into the equation allowed us to estimate the joint’s t_{
r
} to approximately 48000 hours, or 5.5 years.

_{ u }of 11.0 MPa, with a standard deviation of 23.2 for ten joints tested. Table 5 contains the results obtained during creep testing with load levels between 100% and 58% of τ

_{ u }.

**Creep test results for loads of 100%, 97%, 84%, 71%, 65% and 58% of τ**
_{
u
}
**with polyurethane adhesive**

POLYURETHANE adhesive | Load [MPa] | Time until rupture [hours] | |||
---|---|---|---|---|---|

Average | Standard deviation | Average | Standard deviation | ||

100 | % da (τ | 11.0 | 3.9 | 0.2 | 6.4 |

97 | % da (τ | 10.7 | 3.7 | 0.5 | 15.3 |

84 | % da (τ | 9.2 | 4.3 | 6.2 | 60.4 |

71 | % da (τ | 7.8 | 5.1 | 62.9 | 44.3 |

65 | % da (τ | 7.1 | 5.6 | 177.2 | 100.3 |

58 | % da (τ | 6.4 | 6.2 | 669.6 | 18.2 |

_{ u }. The secondary region corresponds to load levels below 7.8 MPa, and presents much lower mechanical strength reduction rates, indicating a tendency to stabilization of the curve. Figure 8 presents the experimental data plotted in logarithmic scale. It shows a tendency towards the alignment of the experimental data, in a way such that a straight line could be drawn as a representation of the joints behavior in logarithmic scale.

_{ 2 }e k

_{ 2 }coefficients from Equation 5, which represent a relation between the load and the lifespan for the polyurethane adhesive.

Where:

n_{
2
} = - 6.77 × 10^{-2};

k_{
2
} = 10.28 MPa/h;

Once again, the experimental data showed great variations on the upper and lower limits related to the lifespan. However, this can be explained by the fact that they are found within the region with tendency towards stabilization of the model curve, where small load variations, in the order of the equipment’s resolution, would have a strong influence on the lifespan of the joints.

## Conclusion

Based on the experimental results, it was possible to evaluate the behavior of the bonded joints with both adhesives as a function of the load applied to them. Results show that the allowable stress of the joints is much lower than the ones found in tensile strength tests. In average, joints loaded above 60% of **τ**_{
u
} account for a relatively small lifespan, something around months.

The proposed model, using the linear regression technique, allowed the determination of two equations, specific for each joint type, which were quite satisfactory in representing the creep behavior and allows the prediction of the joints lifespan in function of the applied loads. It was possible to determine safe region for the use of the bonded joints being that a tendency for the curve stabilization was observed, and consequently, a limit to which joint subject to lower loads would have long lifespans.

Although the mathematical models represent in a satisfactory way the behavior of bonded joints, it should be taken into consideration that the proposed equation is only one of the predictive techniques, and that for an even more reliable modeling, it is necessary to evaluate the results varying temperature, adhesive, surface treatment, adhesive thickness and scale factor analysis.

## Declarations

## Authors’ Affiliations

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## Copyright

This article is published under license to BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.