Mode I critical fracture energy of adhesively bonded joints between glass fiber reinforced thermoplastics
© Mahaphasukwat et al.; licensee Springer. 2015
Received: 6 January 2015
Accepted: 25 February 2015
Published: 7 March 2015
The Erratum to this article has been published in Applied Adhesion Science 2015 3:11
Critical fracture energies of adhesively bonded joints under mode I constant separation were experimentally investigated. Double cantilever beam (DCB) specimens comprising polyamide 6 (PA6) based fiber reinforced thermoplastics (GFRTP) were utilized for the experiments. The adherends of the joints were bonded with three different types of adhesives such as polyurethane and acrylates. A surface treatment method with a primer was applied to pre-bonded surface, matching with the different adhesives, which results in five combinations.
Strongest combination, Plexus Primer PC120 and Plexus AO420, exhibited 2.95 kJ/m2 in mode I critical fracture energy, which is much higher than those of ordinary epoxy adhesive and similar to those of rubber-modified very-ductile epoxy adhesives. Therefore, it is confirmed that adhesive bonding can be applied to join PA6 based GFRTP even for structural use, although the material is thought too difficult to bond adhesively.
Adhesive bonding technology and applications for composite materials are of particular importance to many industries because of their ability to support and improve the features of future’s products such as light-weight transportations. Let us take the automotive industry as an example; the steel car structure is mainly used in present day automotive industries. Substituting steel with aluminum alloy or composite materials wherever possible can provide many benefits to a car performance, such as higher fuel efficiency by weight reduction, stiffer chassis and manageable weight distribution for better handling, design variety, etc. [1,2]. Composite materials such as glass fiber or carbon fiber reinforced plastics (GFRP or CFRP) are the most promising in terms of reducing the weight of a car body in white.
The application of adhesive bonding is also very beneficial because it makes the bonding between different materials possible and it also provides more uniform stress distribution in the joint area over conventional mechanical fasteners that expose the material to concentrated stress . For composite materials, reducing stress concentration in joints is crucial, and dissimilar materials joining with metals is also ineluctable to fabricate real car structures. Thus, adhesive bonding is very promising as one of joining methods for the future’s car structures consisting of composite materials
The matrix resin for fiber reinforced plastics (FRP) is gradually changing from thermosetting type such as epoxy resins to thermoplastic type such as polyamide resins because the forming time of thermoplastic composites is much shorter than that of thermoplastic composites, leading to shorter cycle times in assembly lines and increased efficiency in production, which is indispensable for the automotive industry.
There are many bonding methods that can be applied to the thermoplastic composites, such as welding. Even for dissimilar materials with thermoplastic composites, welding can be applied as thermo-melted fusion bonding methods [4,5]. On the other hand, even though the use of adhesives is still a promising joining method for thermoplastic composites , it is thought that those materials are hard to bond because of their low surface energies. To identify the most reliable bonding method that can be applied in the making of structures, consideration in terms of cost, time, and efficiency, should be investigated.
However, research on adhesively bonded joints of thermoplastic composites is incipient still now. Therefore, this research focuses on the strength of joints between glass fiber reinforced thermoplastics (GFRTP) as the adherends, bonded with three different types of adhesive. Further study and exploration on the use of different surface pretreatments, such as primer pretreatment matching to various kinds of adhesives available in market, have been carried out.
Furthermore, methods to measure the strength of the bonded joints are also very important. In the past, designs for engineering structures have been dominated by using approaches based on mechanics of materials, in which allowable stress or strains are applied as the strength criteria. However, such approaches have a difficulty because stress singularity may occur near the edges of adhesive layer and that leads to the dependency of predicted strength on the mesh size for finite element methods. Recent approaches on the design for strength of structures, fracture mechanics offer several criteria for evaluating the strength of structures including flaws  or adhesively bonded joints [8-14].
To test for the strength of adhesively bonded joints in this research, double cantilever beam (DCB) specimens were prepared and used in the experiments. Based on linear elastic fracture mechanic (LEFM), the energy release rate approach was applied to obtain the critical fracture energies of the joints. Fracture in adhesive layer may occur in three different loading modes: mode I (opening), mode II (forward shear), and mode III (tearing). However, this research will focus on the mode I loading condition.
GFRTP properties (provided by manufacturer)
Tensile Strength (MPa)
Tensile Modulus (GPa)
Flexural Strength (MPa)
Flexural Modulus (GPa)
Processing temperature (°C)
Main application use
TEPEX® dynalite 102
automotive, protection, consumer, sports, miscellaneous
Primer P (Plexus Primer/Conditioner PC120, Illinois Tool Works Inc., USA), which was designed to improve long term durability for adhesively bonded joins with acrylate adhesive when used for aluminum or stainless steel assemblies .
Adhesive A (Sikaflex-252, Sika AG, Switzerland) is a 1-component, moisture cured, polyurethane adhesive .
Adhesive B (Plexus MA300, Illinois Tool Works Inc., USA) is a two-part methacrylate adhesive designed for structural bonding with high strength and stiffness as well as the ability to bond a wide range of materials .
Adhesive C (Plexus AO420, Illinois Tool Works Inc., USA) is also a two-part methacrylate adhesive designed for structural bonding. It provides a unique combination of high strength, good fatigue endurance, high impact resistance, and toughness .
Adhesive A without Primer: A
Adhesive B without Primer: B
Adhesive B with Primer P: BP
Adhesive C without Primer: C
Adhesive C with Primer P: CP
Releasing film (Teflon) of 25 × 200 mm2 was placed on one side of a GFRTP plate to ensure pre-crack of 25 mm-length.
A narrow releasing film (Teflon) of approximately 10 × 200 mm2 was placed on the other end as a shim to ensure an adhesive layer thickness of approximately 0.1 mm.
The specific type of adhesive was applied on the surface and spread evenly throughout.
The other GFRTP plate was placed on the top.
- 5.The plates were inserted into a silicon dam surrounding them in order to achieve proper alignment and were transferred to a hydraulic press, as shown in Figure 2.
Sufficient pressure, approximately 0.53 MPa (15 MPa-gage pressure), was applied to the area (25 × 200 mm2) to achieve good adhesive distribution over the surfaces of the plates and kept for the required time to cure each adhesive.
The bonded plates were released and cut it into specimen size of 25 mm in width.
Two piano hinges were installed on the 25 mm pre-cracked side to an obtained specimen of the final shape as shown in Figure 1.
Results and discussion
for systems which energy dissipation is limited to the crack tip region. Here, W is the external work, U is the stored elastic energy, and A is the crack area. The crack will propagate when this applied energy release rate reaches the critical value, g C , related to the fracture toughness in mode I, g I .
In the experiments, since relatively soft adhesives were utilized, the crack tips were difficult to identify visually, the process zones were quite large. Thus, it was difficult to calculate g I from visually observed crack length. Chaves et al. proposed a crack equivalent method by energy release rate can be determined without crack length even for mixed mode conditions . Based on the theory proposed by Chaves and the simple beam theory, a following method that is simpler and can be used only for mode I loading was derived and applied to the test results.
g IC,avg (kJ/m 2 )
The effect of primer P was drastic because the use increased the critical fracture energies of adhesive B and C approximately three times. The results show that the combination of adhesive C (Plexus AO420) and primer P (Plexus Primer PC120) exhibited the strongest value of 2.95 kJ/m2 that is much higher than those of ordinary epoxy adhesives and not inferior to the critical fracture energy of the most ductile epoxy adhesives such as CTBN modified epoxy adhesives.
Adhesive A (Sikaflex-252), which is polyurethane, was not combined with any primer in this research. The reason is only due to the situation that the authors did not have any primer appropriate for polyurethane adhesives. Polyurethane adhesives are usually utilized with surface treatment methods such as flame treatments and surface primers when applied to thermoplastics because the materials have low surface energy and are difficult to bond. The possibility that adhesive A exhibits higher strength with surface treatments cannot be denied. Thus, the results of this research do not imply the superiority of acrylate adhesives to polyurethane adhesives, but demonstrate the applicability of those types of adhesives to structural use.
PA 6 based thermoplastic composites can be bonded by adhesive. The strength is not weak even if surface treatment is not applied and very high when proper surface treatment is applied and it matches to the type of adhesive.
Acrylate adhesives B (Plexus MA300) and C (Plexus AO420) have enough strength compared with ordinary epoxy adhesives. The critical fracture energies without primer treatment are 403 J/m2 for adhesives B and 918 J/m2 for adhesives C.
Polyurethane adhesive A (Sikaflex-252) has a critical fracture energy of 577 J/m2, which is higher than that of adhesives B.
When primer P (Plexus Primer PC120) is used, the critical fracture energy of DCB specimens increases much. For instance, adhesives B with primer P and adhesives C with primer P exhibited 1.27 kJ/m2 and 2.95 kJ/m2 in critical fracture energy, respectively. The values are approximately three times to those without primer treatment.
The critical fracture energy with adhesive C and primer P, i.e. 2.95 kJ/m2 is not inferior to the maximum values obtained from sophisticated ductile epoxy adhesives modified with rubber particles.
Sika Japan Ltd. and ITW Performance Polymers & Fluids Japan are greatly acknowledged for providing us adhesives.
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